High solids-content PTFE nanoemulsions


E. Marchese, V. Kapeliouchko

Ausimont S.p.A., p.le Donegani 5/6, 15047 Spinetta Marengo (AL), Italia


 




Background


During last years, a great deal of publications has been devoted to nanostructured materials (1,2). Examples of such materials include either inorganics like ceramic, metal, semiconductor composites, either polymeric or polymer/inorganic nanostructures (3). For constructing these nanocomposites it is necessary to obtain polymer nanoparticles (<50nm) by industrially based technology. Such nanoparticles could also be extremely useful as construction material in quickly developing nanotechnology applications.

Polytetrafluoroethylene (PTFE) because of its unique combination of high heat and chemical resistance together with high purity, lubricity, dielectric properties etc. has been an indispensable material for industry (4), and for this reason there is a strong necessity for synthesis of PTFE nanoparticles that can be used for nanocomposites exalting conventional PTFE premium characteristics.

Basically PTFE is manufactured by suspension or emulsion polymerization (4). Suspension polymer is a some-millimeters-dimension reactor bead that after postreatment and milling could arrive to some microns.

Emulsion polymerization latex has an average particle size of about 150?300 nm (4), and by using low reaction conversion it is possible to obtain 100nm particles (5). In relation to these conventional methods, Ausimont?s technology of perfluorinated microemulsion polymerization (6,7) permits to obtain particles from 10 to 100nm. In comparison with other cases of PTFE microemulsion polymerization (8,9,10) which use low conversions, high surfactant concentration etc., the Ausimont?s technology gives industrially PTFE nanoemulsions (10...100nm) at high conversion and latex concentration (20-40 wt.%) and relatively low surfactant content.
 
 
 
 

Results


Through Ausimont technology, for the first time applied systematically to the polymerisation of PTFE, we were able to obtain nanoemulsion of PTFE and slightly modified PTFE with no need of liquefying the monomer, nor to use very high ratio of surfactant to polymer, as requested by usual polymerisation in microemulsion. We found that, varying the amount of PFPE microemulsion and with the nature and quantity of comonomer, it is possible to get not only very tiny PTFE particles but also very different morphologies .

Two extreme cases can be described :

  1. without comonomer and with a high ratio of microemulsion to polymer, anyway less than 0.03, PTFE particles with a high (10 - 100) length over diameter ratio (L/D) are attained;
  2. using the right amount of comonomer and perfluorinated microemulsion, it is possible to get very small (10 - 60 nm) and spherical particles of PTFE.
It is also possible to choose the polymerisation condition in such a fashion that mixture of rod-like and spherical particles are both present at the end of the polymerisation.
 
 
 
 

Classic PTFE composites


There are two principal classes of PTFE composites materials: one of them use PTFE as filler and another is filled PTFE. Some examples of using PTFE as filler are:

and many other applications.

A large portfolio of filled PTFE compositions has been developed based on fillers as glass fibers, carbon/graphite, bronze, molybdenum disulfide, mica etc.(14,15). These filled compounds show enhanced physical properties such as compressive strength, creep resistance, wear and abrasion resistance etc.
 
 
 

Discussion

 
 
 

We think all these classes of speciality composite materials could benefit by using PTFE nanoparticles that enhance characteristics such as higher contact surface, better rheological properties, homogeneity etc.

Further, PTFE nanoemulsions could be useful to create substantially new materials,-nanocomposites, particularly in the nanotechnology field. For example, it has been described that PTFE nanoemulsions could be advantageously used for ultra-low dielectric constant thin film for ULSI applications (16-18).

One of the principal problems in using PTFE for nanocomposites is the difficulty for adhesion with other materials (19). The microemulsion polymerization together with various "core-shell" techniques, studied and available in Ausimont for different fluorinated and hydrogenated monomers combinations, permits to obtain materials with modified or grafted shell with good potential for getting nanostructured materials suitable for nanotechnology applications.
 
 
 
 
 

References

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